1979-1982: Director of the Department of Policy Studies of Education Ministry and member of its Party Committee.
1982-1985: Vice Minister of Education and member of its Party Committee.
1982-1992: Member of the Central Commission for Discipline Inspection of the CPC Central Committee.
1985-1987: Deputy Director of the State Education Committee and member of its Party Committee.
1987-1988: Deputy Director of the State Education Committee and member of its Party group and Secretary of Party Committee of the Chinese University of Science and Technology.
1993-1997: State councilor, Director of the National Women and Children's Working Committee, Director of the State Family Planning Committee.
1998 -2003: Vice Chairperson of the Standing Committee of the Ninth National People's Congress.
Peng was President of the Seventh and Eighth Executive Committees of the Red Cross Society of China. She was also a member of the 14th and 15th CPC Central Committees.
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